Synthesis and structural characterization of metal-organic frameworks with the mellitate linker M2(OH)2[C12O12H2].2H2O (M = Al, Ga, In) MIL-116
Identifieur interne : 000406 ( Main/Repository ); précédent : 000405; suivant : 000407Synthesis and structural characterization of metal-organic frameworks with the mellitate linker M2(OH)2[C12O12H2].2H2O (M = Al, Ga, In) MIL-116
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Abstract
A new series of isostructural MOF-type carboxylates called MIL-116 (M2(OH)2[C12O12H2].2H2O), was synthesized from the combination of mellitic acid and trivalent p cations M = Al3+, Ga3+ or In3+. Their structures were analyzed either by single-crystal microdiffraction using the synchrotron radiation beamline (ID13 station at ESRF, Grenoble) or solved from powder X-ray diffraction. The 3D hybrid framework is built up from the connection of infinite straight chains of metal-centered octahedra sharing trans corners linked to each other through the mellitate ligands. Here the ligand acts as octadentate linker with four of the carboxylic groups involved in the M-O-C bondings. The two other carboxylate arms remain non-bonded under their protonated form. This represents a rare case of the occurrence of both non-bonding and bonding organic functionalities in a MOF-type solid. Within the tunnels are located water species that interact with the non-coordinated -COOH groups pointing towards the channel.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Synthesis and structural characterization of metal-organic frameworks with the mellitate linker M<sub>2</sub>(OH)<sub>2</sub>[C<sub>12</sub>O<sub>12</sub>H<sub>2</sub>].2H<sub>2</sub>O (M = Al, Ga, In) MIL-116</title><author><name sortKey="Volkringer, Christophe" uniqKey="Volkringer C">Christophe Volkringer</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Institut Lavoisier de Versailles, Porous Solids Group</s1><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>France</country><wicri:noRegion>Porous Solids Group</wicri:noRegion><wicri:noRegion>Institut Lavoisier de Versailles, Porous Solids Group</wicri:noRegion></affiliation></author><author><name sortKey="Loiseau, Thierry" uniqKey="Loiseau T">Thierry Loiseau</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Institut Lavoisier de Versailles, Porous Solids Group</s1><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>France</country><wicri:noRegion>Porous Solids Group</wicri:noRegion><wicri:noRegion>Institut Lavoisier de Versailles, Porous Solids Group</wicri:noRegion></affiliation></author><author><name sortKey="Guillou, Nathalie" uniqKey="Guillou N">Nathalie Guillou</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Institut Lavoisier de Versailles, Porous Solids Group</s1><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>France</country><wicri:noRegion>Porous Solids Group</wicri:noRegion><wicri:noRegion>Institut Lavoisier de Versailles, Porous Solids Group</wicri:noRegion></affiliation></author><author><name sortKey="Ferey, Gerard" uniqKey="Ferey G">Gérard Ferey</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Institut Lavoisier de Versailles, Porous Solids Group</s1><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>France</country><wicri:noRegion>Porous Solids Group</wicri:noRegion><wicri:noRegion>Institut Lavoisier de Versailles, Porous Solids Group</wicri:noRegion></affiliation></author><author><name sortKey="Popov, Dmitry" uniqKey="Popov D">Dmitry Popov</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>ESRF</s1><s3>FRA</s3><sZ>5 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>France</country><wicri:noRegion>ESRF</wicri:noRegion><wicri:noRegion>ESRF</wicri:noRegion></affiliation></author><author><name sortKey="Burghammer, Manfred" uniqKey="Burghammer M">Manfred Burghammer</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>ESRF</s1><s3>FRA</s3><sZ>5 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>France</country><wicri:noRegion>ESRF</wicri:noRegion><wicri:noRegion>ESRF</wicri:noRegion></affiliation></author><author><name sortKey="Riekel, Christian" uniqKey="Riekel C">Christian Riekel</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>ESRF</s1><s3>FRA</s3><sZ>5 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>France</country><wicri:noRegion>ESRF</wicri:noRegion><wicri:noRegion>ESRF</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="inist">14-0019972</idno><date when="2013">2013</date><idno type="stanalyst">PASCAL 14-0019972 INIST</idno><idno type="RBID">Pascal:14-0019972</idno><idno type="wicri:Area/Main/Corpus">000310</idno><idno type="wicri:Area/Main/Repository">000406</idno></publicationStmt><seriesStmt><idno type="ISSN">1293-2558</idno><title level="j" type="abbreviated">Solid state sci.</title><title level="j" type="main">Solid state sciences</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Carboxylates</term><term>Gallium</term><term>Hydrothermal synthesis</term><term>Indium</term><term>Ligands</term><term>Mellitic acid</term><term>Metal organic framework</term><term>Monocrystals</term><term>Organometallic compounds</term><term>Synchrotron radiation</term><term>Tunnel effect</term><term>XRD</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Composé organométallique</term><term>Charpente organométallique</term><term>Carboxylate</term><term>Acide mellitique</term><term>Rayonnement synchrotron</term><term>Diffraction RX</term><term>Ligand</term><term>Effet tunnel</term><term>Gallium</term><term>Indium</term><term>Synthèse hydrothermale</term><term>Monocristal</term><term>8105L</term><term>6166H</term><term>8105Z</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">A new series of isostructural MOF-type carboxylates called MIL-116 (M<sub>2</sub>(OH)<sub>2</sub>[C<sub>12</sub>O<sub>12</sub>H<sub>2</sub>]<sub>.</sub>2H<sub>2</sub>O), was synthesized from the combination of mellitic acid and trivalent p cations M = Al<sup>3+</sup>, Ga<sup>3+</sup> or In<sup>3+</sup>. Their structures were analyzed either by single-crystal microdiffraction using the synchrotron radiation beamline (ID13 station at ESRF, Grenoble) or solved from powder X-ray diffraction. The 3D hybrid framework is built up from the connection of infinite straight chains of metal-centered octahedra sharing trans corners linked to each other through the mellitate ligands. Here the ligand acts as octadentate linker with four of the carboxylic groups involved in the M-O-C bondings. The two other carboxylate arms remain non-bonded under their protonated form. This represents a rare case of the occurrence of both non-bonding and bonding organic functionalities in a MOF-type solid. Within the tunnels are located water species that interact with the non-coordinated -COOH groups pointing towards the channel.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>1293-2558</s0></fA01><fA03 i2="1"><s0>Solid state sci.</s0></fA03><fA05><s2>26</s2></fA05><fA08 i1="01" i2="1" l="ENG"><s1>Synthesis and structural characterization of metal-organic frameworks with the mellitate linker M<sub>2</sub>(OH)<sub>2</sub>[C<sub>12</sub>O<sub>12</sub>H<sub>2</sub>].2H<sub>2</sub>O (M = Al, Ga, In) MIL-116</s1></fA08><fA11 i1="01" i2="1"><s1>VOLKRINGER (Christophe)</s1></fA11><fA11 i1="02" i2="1"><s1>LOISEAU (Thierry)</s1></fA11><fA11 i1="03" i2="1"><s1>GUILLOU (Nathalie)</s1></fA11><fA11 i1="04" i2="1"><s1>FEREY (Gérard)</s1></fA11><fA11 i1="05" i2="1"><s1>POPOV (Dmitry)</s1></fA11><fA11 i1="06" i2="1"><s1>BURGHAMMER (Manfred)</s1></fA11><fA11 i1="07" i2="1"><s1>RIEKEL (Christian)</s1></fA11><fA14 i1="01"><s1>Institut Lavoisier de Versailles, Porous Solids Group</s1><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></fA14><fA14 i1="02"><s1>ESRF</s1><s3>FRA</s3><sZ>5 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ></fA14><fA20><s1>38-44</s1></fA20><fA21><s1>2013</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>11118</s2><s5>354000507490440060</s5></fA43><fA44><s0>0000</s0><s1>© 2014 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>69 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>14-0019972</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Solid state sciences</s0></fA64><fA66 i1="01"><s0>FRA</s0></fA66><fC01 i1="01" l="ENG"><s0>A new series of isostructural MOF-type carboxylates called MIL-116 (M<sub>2</sub>(OH)<sub>2</sub>[C<sub>12</sub>O<sub>12</sub>H<sub>2</sub>]<sub>.</sub>2H<sub>2</sub>O), was synthesized from the combination of mellitic acid and trivalent p cations M = Al<sup>3+</sup>, Ga<sup>3+</sup> or In<sup>3+</sup>. Their structures were analyzed either by single-crystal microdiffraction using the synchrotron radiation beamline (ID13 station at ESRF, Grenoble) or solved from powder X-ray diffraction. The 3D hybrid framework is built up from the connection of infinite straight chains of metal-centered octahedra sharing trans corners linked to each other through the mellitate ligands. Here the ligand acts as octadentate linker with four of the carboxylic groups involved in the M-O-C bondings. The two other carboxylate arms remain non-bonded under their protonated form. This represents a rare case of the occurrence of both non-bonding and bonding organic functionalities in a MOF-type solid. Within the tunnels are located water species that interact with the non-coordinated -COOH groups pointing towards the channel.</s0></fC01><fC02 i1="01" i2="3"><s0>001B80A05Z</s0></fC02><fC02 i1="02" i2="3"><s0>001B60A66H</s0></fC02><fC03 i1="01" i2="3" l="FRE"><s0>Composé organométallique</s0><s5>01</s5></fC03><fC03 i1="01" i2="3" l="ENG"><s0>Organometallic compounds</s0><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Charpente organométallique</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Metal organic framework</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Armazòn organometálico</s0><s5>02</s5></fC03><fC03 i1="03" i2="3" l="FRE"><s0>Carboxylate</s0><s5>03</s5></fC03><fC03 i1="03" i2="3" l="ENG"><s0>Carboxylates</s0><s5>03</s5></fC03><fC03 i1="04" i2="3" l="FRE"><s0>Acide mellitique</s0><s2>NK</s2><s5>04</s5></fC03><fC03 i1="04" i2="3" l="ENG"><s0>Mellitic acid</s0><s2>NK</s2><s5>04</s5></fC03><fC03 i1="05" i2="3" l="FRE"><s0>Rayonnement synchrotron</s0><s5>05</s5></fC03><fC03 i1="05" i2="3" l="ENG"><s0>Synchrotron radiation</s0><s5>05</s5></fC03><fC03 i1="06" i2="3" l="FRE"><s0>Diffraction RX</s0><s5>06</s5></fC03><fC03 i1="06" i2="3" l="ENG"><s0>XRD</s0><s5>06</s5></fC03><fC03 i1="07" i2="3" l="FRE"><s0>Ligand</s0><s5>07</s5></fC03><fC03 i1="07" i2="3" l="ENG"><s0>Ligands</s0><s5>07</s5></fC03><fC03 i1="08" i2="3" l="FRE"><s0>Effet tunnel</s0><s5>08</s5></fC03><fC03 i1="08" i2="3" l="ENG"><s0>Tunnel effect</s0><s5>08</s5></fC03><fC03 i1="09" i2="3" l="FRE"><s0>Gallium</s0><s2>NC</s2><s5>09</s5></fC03><fC03 i1="09" i2="3" l="ENG"><s0>Gallium</s0><s2>NC</s2><s5>09</s5></fC03><fC03 i1="10" i2="3" l="FRE"><s0>Indium</s0><s2>NC</s2><s5>10</s5></fC03><fC03 i1="10" i2="3" l="ENG"><s0>Indium</s0><s2>NC</s2><s5>10</s5></fC03><fC03 i1="11" i2="3" l="FRE"><s0>Synthèse hydrothermale</s0><s5>11</s5></fC03><fC03 i1="11" i2="3" l="ENG"><s0>Hydrothermal synthesis</s0><s5>11</s5></fC03><fC03 i1="12" i2="3" l="FRE"><s0>Monocristal</s0><s5>15</s5></fC03><fC03 i1="12" i2="3" l="ENG"><s0>Monocrystals</s0><s5>15</s5></fC03><fC03 i1="13" i2="3" l="FRE"><s0>8105L</s0><s4>INC</s4><s5>71</s5></fC03><fC03 i1="14" i2="3" l="FRE"><s0>6166H</s0><s4>INC</s4><s5>72</s5></fC03><fC03 i1="15" i2="3" l="FRE"><s0>8105Z</s0><s4>INC</s4><s5>73</s5></fC03><fN21><s1>020</s1></fN21><fN44 i1="01"><s1>OTO</s1></fN44><fN82><s1>OTO</s1></fN82></pA></standard></inist></record>Pour manipuler ce document sous Unix (Dilib)
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